Chemistry 28 - The Carbon Cycle



The Carbon Cycle is a complex series of processes through which all of the carbon atoms in existence rotate. The same carbon atoms in your body today have been used in countless other molecules since time began. The wood burned just a few decades ago could have produced carbon dioxide which through photosynthesis became part of a plant. When you eat that plant, the same carbon from the wood which was burnt can become part of you. The carbon cycle is the great natural recycler of carbon atoms. Unfortunately, the extent of its importance is rarely stressed enough. Without the proper functioning of the carbon cycle, every aspect of life could be changed dramatically.


We believe that it's vital to understand how the carbon cycle works in order to see the danger of it not working. Therefore, let's look at a sample carbon cycle and explore how carbon atoms move through our natural world. Plants, animals, and soil interact to make up the basic cycles of nature. In the carbon cycle, plants absorb carbon dioxide from the atmosphere and use it, combined with water they get from the soil, to make the substances they need for growth. The process of photosynthesis incorporates the carbon atoms from carbon dioxide into sugars. Animals, such as the rabbit pictured here, eat the plants and use the carbon to build their own tissues. Other animals, such as the fox, eat the rabbit and then use the carbon for their own needs. These animals return carbon dioxide into the air when they breathe, and when they die, since the carbon is returned to the soil during decomposition. The carbon atoms in soil may then be used in a new plant or small microorganisms. Ultimately, the same carbon atom can move through many organisms and even end in the same place where it began. Herein lies the fascination of the carbon cycle; the same atoms can be recycled for millennia!




Chemistry 28 - Carbon Dating video

Chemistry 28 - Carbon Dating

Does Carbon dating refers to the dating of carbon atoms?
No! Definitely not (:

Here's the explanation of carbon dating:

Radiocarbon dating, or carbon dating, is a radiometric dating method that uses the naturally occurring radioisotope carbon-14 (14C) to determine the age of carbonaceous materials up to about 58,000 to 62,000 years.[1] Raw, i.e. uncalibrated, radiocarbon ages are usually reported in radiocarbon years "Before Present" (BP), "Present" being defined as AD 1950. Such raw ages can be calibrated to give calendar dates.

One of the most frequent uses of radiocarbon dating is to estimate the age of organic remains from archaeological sites. When plants fix atmospheric carbon dioxide (CO2) into organic material during photosynthesis they incorporate a quantity of 14C that approximately matches the level of this isotope in the atmosphere (a small difference occurs because of isotope fractionation, but this is corrected after laboratory analysis). After plants die or they are consumed by other organisms (for example, by humans or other animals) the 14C fraction of this organic material declines at a fixed exponential rate due to the radioactive decay of 14C. Comparing the remaining 14C fraction of a sample to that expected from atmospheric 14C allows the age of the sample to be estimated.

The technique of radiocarbon dating was developed by Willard Libby and his colleagues at the University of Chicago in 1949. Emilio Segrè asserted in his autobiography that Enrico Fermi suggested the concept to Libby in a seminar at Chicago that year. Libby estimated that the steady state radioactivity concentration of exchangeable carbon-14 would be about 14 disintegrations per minute (dpm) per gram. In 1960, he was awarded the Nobel Prize in chemistry for this work. He first demonstrated the accuracy of radiocarbon dating by accurately estimating the age of wood from an ancient Egyptian royal barge for which the age was known from historical documents.


abstracted from: http://en.wikipedia.org/wiki/Radiocarbon_dating


Chemistry 28 - Conservation of Mass
Watch the video of Conservation of Mass here: http://www.brainpop.com/science/matterandchemistry/conservationofmass/


If you can't watch it, below is the summary: (:






Basically, The law of conservation refers that all matters cannot disappear or appear out of the thin air. They are either broken down, or rearranged to form another compound.

Hope it helped (:


Chemistry 27 - Ionic and Covalent Bonding Video

Chemistry 26 - Covalent Bond video

Chemistry 25 - Oxidation




Chemistry 24 - Some interesting facts (:
  • "Ionized water" is nothing more than sales fiction; the term is meaningless to chemists.
  • Pure water (that is, water containing no dissolved ions) is too unconductive to undergo signficant electrolysis by "water ionizer" devices.
  • Pure water can never be alkaline or acidic, nor can it be made so by electrolysis. Alkaline water mustcontain metallic ions of some kind — most commonly, sodium, calcium or magnesium.
  • The idea that one must consume alkaline water to neutralize the effects of acidic foods is ridiculous; we get rid of excess acid by exhaling carbon dioxide.
  • If you do drink alkaline water, its alkalinity is quickly removed by the highly acidic gastric fluid in the stomach.
  • Uptake of water occurs mainly in the intestine, not in the stomach. But when stomach contents enter the intestine, they are neutralized and made alkaline by the pancreatic secretions — so all the water you drink eventually becomes alkaline anyway.
  • The claims about the health benefits of drinking alkaline water are not supported by credible scientific evidence.
  • "Ionized"/alkaline water is falsely claimed to be an anti-oxidant. It is actually an oxidizing agent, as can be seen by its ability to decolorize iodine (see video)
  • There is nothing wrong with drinking slightly acidic waters such as rainwater. "Body pH" is a meaningless concept; different parts of the body (and even of individual cells) can have widely different pH values. The pH of drinking water has zero effect on that of the blood or of the body's cells.
  • If you really want to de-acidify your stomach (at the possible cost of interfering with protein digestion), why spend hundreds of dollars for an electrolysis device when you can take calcium-magnesium pills,Alka-Seltzer or Milk of Magnesia?
  • Electrolysis devices are generally worthless for treating water for health enhancement, removal of common impurities, disinfection, and scale control. Claims that "ionized" waters are antioxidants are untrue; hypochlorites (present in most such waters) are in fact oxidizing agents.

abstracted from: http://www.chem1.com/CQ/ionbunk.html

Chemistry 23 - Menthol

Menthol is an organic compound naturally occurring in mint plants. It is also synthetically manufactured. Menthol is widely used in a number of products and features certain therapeutic qualities. It was first isolated from peppermint oil in 1771 in the West, but it may have been in use in Japan for much longer.

Most of menthol's uses are related to its stimulation of the skin's cold receptors. This property makes menthol produce a cooling effect when inhaled or applied to the skin. Similarly to the capsaicin chemical found in hot peppers, which stimulates heat receptors, menthol does not actually change the skin's temperature, but merely produces the sensation of temperature change.

Because of its cooling effect, menthol is used in products meant to relieve skin irritation, sore throat, or nasal congestion. It may be used to treat sunburn, fever, or muscle aches as well. In traditional Asian medicine, menthol may be prescribed for nausea, diarrhea, indigestion, headache, cold, or sore throat. When used as a supplement for health reasons, menthol is usually taken in the form of peppermint oil. Products that commonly contain menthol include toothpaste, cough drops, lip balm, mouthwash, gum, and cigarettes.

Practitioners of homeopathic medicine believe that menthol can interfere with the efficacy of homeopathic remedies, and some even go so far as to advise against the use of mint toothpaste. Another common claim against menthol is thatmenthol cigarettes are more dangerous than regular cigarettes, but this has no scientific basis. The idea may be rooted in the fact that African American smokers have both a higher incidence of cigarette-related cancers and a higher preference for menthol cigarettes than smokers of other backgrounds. However, there is no evidence these two statistics are causally related. All types of cigarettes pose significant health risk.

Menthol has very low toxicity, although menthol poisoning is possible if large quantities are consumed. However, any ill effects from the use of mentholare extremely rare. Many people around the world enjoy the cooling sensation of menthol in gum, candy, lip gloss, and other products.




abstracted from: http://www.wisegeek.com/what-is-menthol.htm


Chemistry 22- Camphor
Picture of Camphor

Camphor is a waxy, white or transparent solid with a strong, aromatic odor.[3] It is a terpenoid with the chemical formula C10H16O. It is found in wood of the camphor laurel (Cinnamomum camphora), a large evergreen tree found in Asia (particularly in Borneo and Taiwan) and also of Dryobalanops aromatica, a giant of the Bornean forests.

It also occurs in some other related trees in the laurel family, notably Ocotea usambarensis. It can also be synthetically produced from oil of turpentine. It is used for its scent, as an ingredient in cooking (mainly in India), as an embalming fluid, in religious ceremonies and for medicinal purposes. A major source of camphor in Asia is camphor basil.
Nor camphor is a camphor derivative with the three methyl groups replaced by hydrogen.

Modern uses include as a plasticizer for cellulose nitrate, as a moth repellent, in embalming, and in fireworks. A form of anti-itch gel currently on the market uses camphor as its active ingredient. Historically it has been used in medicine.

Camphor is readily absorbed through the skin and produces a feeling of cooling similar to that of menthol and acts as slight local anesthetic; however, it is poisonous when ingested and can cause seizures, mental confusion, irritability, and neuromuscular hyperactivity.










Chemistry 21 - Revision for Formulae
Writing a substance using the chemical symbol is the chemical formula of the substance

A Chemical Formula consists of:

· The chemical symbol of the element

· The number of atoms (numbers after the chemical symbol. If there is no subscript, it means there is only one atom of the element)

e.g. N₂ : 1 type of element, nitrogen. Total no of atoms: 2

Why does an atom become an ion?

è The reason is because these atoms want to have a full and balanced valence shell which consists of 8 electrons.

è Hence, these atoms will either lose or gain electrons to become either an anion or a cation respectively.

è Ions are an ion is an atom or molecule in which the total number of electrons is not equal to the total number of protons.

v Atoms that belong to groups 1, 2, 3 and 4 usually lose electrons to achieve a full valence shell.

v These atoms belong to the metallic group.

v Atoms that belong to groups 5, 6 and 7 usually gain electrons to achieve a full valence shell.

v These atoms belong to the non-metallic group.

General rules to writing chemical formulae:

v Always write the metallic (positive ion/cation) part first.

v The overall charge of the compound is always 0. The total + and – charges are equal.

v The number of each ion required is written as a subscript. Eg. MgCl

v If the number of polyatomic ion required is more than one, brackets are required. Eg Mg(OH)


Chemistry 20- Melting points
Janelle asked why tungsten was used to the filament of the light bulbs instead of copper. Here are the explanations to it.

Basic Information about tungsten:

b0074.gif

Name: Tungsten
Symbol: W
Atomic Number: 74
Atomic Mass: 183.84 amu
Melting Point: 3410.0 °C (3683.15 K, 6170.0 °F)
Boiling Point: 5660.0 °C (5933.15 K, 10220.0 °F)
Number of Protons/Electrons: 74
Number of Neutrons: 110
Classification: Transition Metal
Crystal Structure: Cubic
Density @ 293 K: 19.3 g/cm3
Color: Silver


Basic Information about Copper:

b0029.gif

Name: Copper
Symbol: Cu
Atomic Number: 29
Atomic Mass: 63.546 amu
Melting Point: 1083.0 °C (1356.15 K, 1981.4 °F)
Boiling Point: 2567.0 °C (2840.15 K, 4652.6 °F)
Number of Protons/Electrons: 29
Number of Neutrons: 35
Classification: Transition Metal
Crystal Structure: Cubic
Density @ 293 K: 8.96 g/cm3
Color: red/orange




Reason:

The reasons why tungsten is chosen is obviously due to the fact that tungsten, has a much more higher melting point than the copper. As the light bulb gives of light, heat will be given off too. Hence, the tungsten will not melt as soon as the copper, giving a longer lasting period. Therefore, tungsten is used.




Chemistry 19- List of Polyatomic ions

Polyatomic ions Names

AsO4-3 arsenate

BO3-3 borate

B4O7-2 tetraborate

BrO3- bromate

BrO- hypobromite

CO3-2 carbonate

CN- cyanide

C2O4-2 oxalate

C2H3O2- acetate

C4H4O6-2 tartrate

ClO4- perchlorate

ClO3- chlorate

ClO2- chlorite

ClO- hypochlorite

CrO4-2 chromate

Cr2O7-2 dichromate

IO4- periodate

IO3- iodate

IO- hypoiodite

HCO3- hydrogen carbonate (bicarbonate)

HSO4- hydrogen sulfate (bisulfate)

HSO3- hydrogen sulfite (bisulfite)

HC2O4- hydrogen oxalate (binoxalate)

HPO4-2 hydrogen phosphate

H2PO4- dihydrogen phosphate

HS- hydrogen sulfide

MnO4- permanganate

NH2- amide

NH4+ ammonium

NO3- nitrate

NO2- nitrite

OH- hydroxide

O2-2 peroxide

PO4-3 phosphate

PO3-3 phosphite

SCN- thiocyanate

S2O3-2 thiosulfate

SO4-2 sulfate

SO3-2 sulfite

SeO4-2 selenate

SiF6-2 hexafluorosilicate

SiO3-2 silicate



Chemistry 18 - Polyatomic ions
What are polyatomic ions?
File-Nitrate-ion-elpot.png

A polyatomic ion, also known as a molecular ion, is a charged species (ion) composed of two or more atoms covalently bonded or of a metal complex that can be considered as acting as a single unit in the context of acid and base chemistry or in the formation of salts. The prefix poly- means many in Greek, but even ions of two atoms are commonly referred to as polyatomic. In older literature, a polyatomic ion is also referred to as a radical, and less commonly, as a radical group. In contemporary usage, the term radical refers to free radicals which are uncharged species with an unpaired electron.

For example, a hydroxide ion is made of one oxygen atom and one hydrogen atom: its chemical formula is (OH). It has a charge of −1. Anammonium ion is made up of one nitrogen atom and four hydrogen atoms: its chemical formula is (NH4)+. It has charge of +1.

A polyatomic ion can often be considered as the conjugate acid or conjugate base of a neutral molecule. For example the sulfate anion, SO42−, is derived from H2SO4 which can be regarded as SO3 + H2O.


reference from: http://en.wikipedia.org/wiki/Polyatomic_ion




Chemistry 17- Properties of transition metals

Properties of Transition Metals

  • malleable
  • ductile
  • conduct heat and electricity well.
  • A "malleable" material is one can be worked with, such as hammered into a flat sheet.
  • A "ductile" material can be turned into wire. Transition metals are good conductors of electricity and heat, as well. For example, copper has been used for electric wiring for decades, and is also used in making cookingutensils.
  • Three transition metals in particular (iron, cobalt and nickel) are also capable of producing a magnetic field.